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Let \\(\\Gamma\\) be the universal central extension of \\(\\pi_1X\\), generated by the same generators, \\(A_1,B_1,\\ldots,A_g,B_g\\), as \\(\\pi_1X\\), together with a central element \\(J\\), subject to the relation \\(\\prod_{i=1}^g[A_i,B_i]=J\\). Given a reductive Lie group, let \\(\\mathcal{R}(G)\\) be the space of semisimple representations of \\(\\Gamma\\) in \\(G\\). In this paper, the authors compute the homotopy groups of \\(\\mathcal{R}(\\mathrm{GL}(n,\\mathbb{C}))\\) and \\(\\mathcal{R}(\\mathrm{U}(p,q))\\), under certain conditions.  For this, they use the correspondence of this theory with the theory of \\(G\\)-Higgs bundles over the associated compact Riemann surface. More precisely, if \\(\\mathcal{M}(G)\\) denotes the moduli space of polystable \\(G\\)-Higgs bundles over \\(X\\), then \\(\\mathcal{M}(G)\\) and \\(\\mathcal{R}(G)\\) are homeomorphic [see \\textit{N. J. Hitchin}, Proc. Lond. Math. Soc., III. 55, 59--126 (1987; Zbl 0634.53045); \\textit{C. T. Simpson}, Publ. Math., Inst. Hautes \u00c9tud. Sci. 79, 47--129 (1994; Zbl 0891.14005); Publ. Math., Inst. Hautes \u00c9tud. Sci. 80, 5--79 (1995; Zbl 0891.14006); \\textit{S. K. Donaldson}, Proc. Lond. Math. Soc., III. 55, 127--131 (1987; Zbl 0634.53046) and \\textit{K. Corlette}, J. Differ. Geom. 28, No. 3, 361--382 (1988; Zbl 0676.58007)]. Then, the \\(L^2\\)-norm of the Higgs field is used as a perfect Morse-Bott function in \\(\\mathcal{M}(\\mathrm{GL}(n,\\mathbb{C}))\\) and \\(\\mathcal{M}(\\mathrm{U}(p,q))\\) to reduce the problem to the computation of the homotopy groups of its minimum subvarieties. In the case of \\(\\mathcal{M}(\\mathrm{GL}(n,\\mathbb{C}))\\), the minimum subvarieties are isomorphic to the moduli spaces of polystable vector bundles over \\(X\\), whose homotopy groups have been calculated by \\textit{G. D. Daskalopoulos} and \\textit{K. K. Uhlenbeck} [Topology 34, No. 1, 203--315 (1995; Zbl 0835.58005)]. When \\(g\\geq 3\\) and \\(n\\) and the degree of the vector bundle appearing in a \\(\\mathrm{GL}(n,\\mathbb{C})\\)-Higgs bundle are coprime, this procedure yields the homotopy groups of \\(\\mathcal{M}(\\mathrm{GL}(n,\\mathbb{C}))\\), hence of \\(\\mathcal{R}(\\mathrm{GL}(n,\\mathbb{C}))\\).  For \\(\\mathcal{M}(\\mathrm{U}(p,q))\\), the minimum subvarieties are isomorphic to the moduli spaces of polystable triples and the authors compute their homotopy groups, using the results of \\textit{S. B. Bradlow, O. Garc\u00eda-Prada, P. Gothen} [Math. Ann. 328, No. 1--2, 299--351 (2004; Zbl 1041.32008)]. When \\(g\\geq 3\\) and \\(p+q\\) and the sum of the degrees of the two vector bundles appearing in a \\(\\mathrm{U}(p,q)\\)-Higgs bundle are coprime, this procedure yields the homotopy groups of \\(\\mathcal{M}(\\mathrm{U}(p,q))\\), hence of 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