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Ist. Mat. Univ. Trieste 39, 421--444 (2007; Zbl 1153.54006), Topol. Proc. 30, No.~1, 279--299 (2006; Zbl 1126.54008), Math. Slovaca 58, No.~3, 325--338 (2008; Zbl 1174.54009)].  As is natural, the pseudocompact-open topology on \\(C(X)\\) is the topology of uniform convergence on the pseudocompact subsets of \\(X\\) and \\(C_{ps}(X)\\) is the space \\(C(X)\\) endowed with this topology. Its dual is denoted by \\( \\Lambda _{ps}(X)\\).  The main result of this paper is related with the separability of \\(\\Lambda _{ps}(X)\\). In fact, in Theorem 4.6 it is stated that, for a Tychonoff space \\(X \\), the following assertions are equivalent: {\\parindent6mm \\begin{itemize}\\item[(a)] \\((\\Lambda _{ps}^{+}(X),d_*)\\) is separable.  \\item[(b)] \\((\\Lambda _{ps}(X),\\|\\cdot\\|_*)\\) is separable. \\item[(c)] \\(X\\) is countable. \\item[(d)] \\((M_{ps}^{+}(X),d)\\) is separable. \\item[(e)] \\((M_{ps}(X),\\|\\cdot\\|)\\) is separable.   \\end{itemize}} The map \\(L:\\Lambda _{ps}(X)\\rightarrow \\Lambda _{\\infty }(X)\\) defined by natural inclusions, with \\(\\Lambda _{\\infty }(X)\\) the dual of \\(C_{\\infty }^{\\ast }(X)\\), enables the authors to get the norm \\(\\|\\lambda \\|_*=\\|L(\\lambda )|_*\\) and the distance \\(d_{\\ast }\\) given by \\(d_{\\ast }(\\lambda ,\\mu )=\\) \\(\\|\\lambda -\\mu \\|_*\\). \\(M(X)\\) is the linear space of all closed regular \\(\\sigma \\)-additive Borel measures defined on the \\(\\sigma \\)-algebra \\(\\mathcal{B}_{0}(X)\\) generated by the closed subsets of \\(X\\), \\(\\|\\mu \\|=|\\mu|(X)\\) and \\(d(\\lambda ,\\mu )=\\) \\(\\|\\lambda -\\mu\\|\\).  In order to get this deep theorem, the authors introduce the notion of \\(pz\\)-spaces: \\(X\\) is a \\(pz\\)-space if every pseudocompact subset of \\(X\\) is contained in a pseudocompact zero subset of \\(X\\). 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