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Endow H with the natural positive cone \\(H^+\\) deduced from the Tomita-Takesaki theory. A continuous linear operator \\(\\Phi\\) on H is called an o. d. homomorphism if \\(\\Phi (H^+)\\subset H^+\\) and \\((\\Phi (\\xi),\\Phi (\\eta))=0\\) whenever \\(\\xi,\\eta \\in H^+\\) and \\((\\xi,\\eta)=0\\). Denote by \\({\\mathcal L}(\\xi,\\eta,H^+)\\) the set of all continuous linear operators \\(\\Phi\\) saisfying \\(\\Phi (H^+)\\subset H^+\\) and \\(\\Phi (\\xi)=\\eta\\) where \\(\\xi\\) and \\(\\eta\\) are two positive cyclic separating vectors. It is proved in this paper that all o. d. homomorphisms in \\({\\mathcal L}(\\xi,\\eta,H^+)\\) are extreme points, and that \\({\\mathcal M}\\) is abelian if and only if for any positive cyclic separating vectors \\(\\xi\\) and \\(\\eta\\), the set of extreme points in \\(L(\\xi,\\eta,H^+)\\) equals the set of o. d. homomorphisms in \\({\\mathcal 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