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It is known that if \\(2\\leq d\\leq q-2\\) every normal rational curve of PG(d,q) forms a \\((q+1)\\)-arc; such arcs are called classical. The author describes and derives several properties of a 10- arc K in PG(4,9) which is not a normal rational curve. This is the first example of a non-classical arc of PG(d,q), where q is odd and \\(2\\leq d\\leq q-2.\\) These interesting properties of K are: it is unique, self-dual, and the group of collineations of PG(4,9) fixing K is isomorphic to the group of linear fractional transformations of GF(q)\\(\\cup \\{\\infty \\}\\). Finally, the author shows that every 9-arc of PG(3,9) is either complete (i.e., not contained in a 10-arc of PG(3,9)) or a normal rational 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