{"entities":{"Q1080289":{"pageid":1091041,"ns":120,"title":"Item:Q1080289","lastrevid":70070313,"modified":"2026-04-13T12:14:34Z","type":"item","id":"Q1080289","labels":{"en":{"language":"en","value":"Fluids with highly directional attractive forces. I. Statistical thermodynamics"}},"descriptions":{"en":{"language":"en","value":"scientific article; zbMATH DE number 3965637"}},"aliases":{},"claims":{"P31":[{"mainsnak":{"snaktype":"value","property":"P31","hash":"fd5912e4dab4b881a8eb0eb27e7893fef55176ad","datavalue":{"value":{"entity-type":"item","numeric-id":56887,"id":"Q56887"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$565AE0CE-F3EF-4D0A-9FC6-E300AB33263F","rank":"normal"}],"P159":[{"mainsnak":{"snaktype":"value","property":"P159","hash":"bced8c439fac7fefc30117e157d359100ab91740","datavalue":{"value":{"text":"Fluids with highly directional attractive forces. I. Statistical thermodynamics","language":"en"},"type":"monolingualtext"},"datatype":"monolingualtext"},"type":"statement","id":"Q1080289$C90E0D4F-9B05-473F-AF54-8A811EB2D74C","rank":"normal"}],"P225":[{"mainsnak":{"snaktype":"value","property":"P225","hash":"69d0a5a96a9952a3bb4ef69b8bf93f134452eb1f","datavalue":{"value":"0598.76004","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q1080289$08F56D2E-F439-49C2-8005-F972E5D827A0","rank":"normal"}],"P27":[{"mainsnak":{"snaktype":"value","property":"P27","hash":"77e6675c0f2b446030bd75a2fcf82109f5842b08","datavalue":{"value":"10.1007/BF01017362","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q1080289$AA1E4350-BCE4-4FAF-80C7-D98A95A971CE","rank":"normal"}],"P16":[{"mainsnak":{"snaktype":"value","property":"P16","hash":"ea66aa70cc422a18110169fe50879ddd6666c2f3","datavalue":{"value":{"entity-type":"item","numeric-id":1080288,"id":"Q1080288"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$FF936EA9-8769-4464-BEC2-45275BC30027","rank":"normal"}],"P200":[{"mainsnak":{"snaktype":"value","property":"P200","hash":"bd988655a64cc18194d4bb8e267ebd8eed41b1a8","datavalue":{"value":{"entity-type":"item","numeric-id":166985,"id":"Q166985"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$D0A6AB01-2F3C-4C35-BFB0-61624837FE21","rank":"normal"}],"P28":[{"mainsnak":{"snaktype":"value","property":"P28","hash":"2ee0f220147ae8bc749a64db56839865dbc4f127","datavalue":{"value":{"time":"+1984-00-00T00:00:00Z","timezone":0,"before":0,"after":0,"precision":9,"calendarmodel":"http://www.wikidata.org/entity/Q1985727"},"type":"time"},"datatype":"time"},"type":"statement","id":"Q1080289$49BF103D-991D-451B-99AC-48955B3BE0A2","rank":"normal"}],"P1448":[{"mainsnak":{"snaktype":"value","property":"P1448","hash":"ce4cf158d751579a04a9391ebc4c22f4751f802d","datavalue":{"value":"A new formulation of statistical thermodynamics is derived for classical fluids of molecules that tend to associate into dimers and possibly higher s-mers due to highly directional attraction. A breakup of the pair potential into repulsive and highly directionally attractive parts is introduced into the expansion of the logarithm of the grand partition function in fugacity graphs.    The bonding by the directional attraction is used to classify the graphs and to introduce a topological reduction which results in the replacement of the fugacity by two variables: singlet density \\(\\rho\\) and monomer density \\(\\rho_ 0\\). Results for the thermodynamic functions as functionals of \\(\\rho\\) and \\(\\rho_ 0\\) are given in the form of graph sums.    Pair correlations are analyzed in terms of a new matrix analog of the direct correlation function. It is shown that the low-density limit is treated exactly, while major difficulties arise when the Mayer expansion, which employs only \\(\\rho\\), is used. The intricate resummations required for the Mayer expansion are illustrated for the case where dimers are the only association products.","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$69DC071F-1714-4535-8DA3-08638A77048D","rank":"normal"}],"P226":[{"mainsnak":{"snaktype":"value","property":"P226","hash":"1f1edb41c1f949323b839603127886e75f99ad23","datavalue":{"value":"76A02","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q1080289$2D9F74D1-33D8-454E-84D9-678F6BD96ED3","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P226","hash":"000aeb7301fb6bd2a8f4af2b68dcce0105de1090","datavalue":{"value":"82B05","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q1080289$786EBA7A-2F1C-4EA5-9EC6-84C4BDDCECEE","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P226","hash":"602385e70a491ba3f02bd41a59a24904cec7e7a0","datavalue":{"value":"82D60","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q1080289$BD7F7B11-733E-4BDB-B1DB-165A19DA3CF4","rank":"normal"}],"P1451":[{"mainsnak":{"snaktype":"value","property":"P1451","hash":"c54532927d8c3fd63e97c77973514a2889929057","datavalue":{"value":"3965637","type":"string"},"datatype":"external-id"},"type":"statement","id":"Q1080289$9210DAA3-77D5-4286-AC59-C21BD8754C7B","rank":"normal"}],"P1450":[{"mainsnak":{"snaktype":"value","property":"P1450","hash":"231ad5d0f6aec0ce770aedb19c34a46b67ca08ea","datavalue":{"value":"classical fluids of molecules","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$65EFE70D-B49F-445F-8603-3793D059FC5C","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"717c9c756b5d0611d6651945ed64c70e937afd30","datavalue":{"value":"dimers","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$E52142DA-1C99-4780-873A-B8A52DADA55C","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"3f5c4d37825038477e6a33425d2a8f996093457e","datavalue":{"value":"highly directional attraction","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$ABE542AD-E5E4-4443-A7FE-AEB31C60B50A","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"ff280caf9df604421532f6eed677240c47c58da8","datavalue":{"value":"breakup of the pair potential","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$6B132B2C-EB05-451F-86EB-47EEBDA46152","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"33df693711cc988c2ab6259e8fdcdb41764da2fc","datavalue":{"value":"expansion of the logarithm","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$3F9CC054-E229-462C-B6D8-9A87EF557A85","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"3669ccdd36aa80bf3136a3c8035e7f0f2386792b","datavalue":{"value":"grand partition function","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$20AF3494-E991-477C-96D9-5B0B1783EDE2","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"24077668a88e629e63d76d0858e00f4f3776a8da","datavalue":{"value":"fugacity graphs","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$0CECE0F2-2C8D-4A36-8006-872D26D190EF","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"8098ac1fc27ee952d69377d705c72d36feb4ea26","datavalue":{"value":"topological reduction","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$2AF1C77B-2C11-4912-AEF4-957B5CF422A9","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"50728620fa88fbaec694146b02301ce4d78d4bde","datavalue":{"value":"singlet density","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$9193C6AB-F9B7-4232-805D-9C571E76E453","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"3d3591ce491476f226a4ae355e881196370eaa82","datavalue":{"value":"monomer density","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$DE85A99B-6C39-4374-BCF3-BEAAB454E20E","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"0f0864902d440da93c171cad99883bfdddf13c41","datavalue":{"value":"Pair correlations","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$F41C827E-CE40-49DB-B305-64E804F4E2B3","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"4828ce08d401aa015c11de127dc02a3493e2373d","datavalue":{"value":"direct correlation function","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$BC2B0B85-F04C-4A45-A136-DD40DC51AB45","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"5a077e0200de1d63084b3e24041dfaee21693ece","datavalue":{"value":"low-density limit","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$D5ECBECA-FA97-4F0A-BF9C-0F5BE7FA6182","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1450","hash":"0111741c1755b887cf92a99e45199f8807ca898d","datavalue":{"value":"Mayer expansion","type":"string"},"datatype":"string"},"type":"statement","id":"Q1080289$6C77BA23-12E5-4577-ACDC-A7F40AF7992F","rank":"normal"}],"P1460":[{"mainsnak":{"snaktype":"value","property":"P1460","hash":"57f7fea50d2ce1b39b695c4a1313582eed405e38","datavalue":{"value":{"entity-type":"item","numeric-id":5976449,"id":"Q5976449"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$0062E2E3-B52B-4CF2-A54A-F4B5CC2D6220","rank":"normal"}],"P223":[{"mainsnak":{"snaktype":"value","property":"P223","hash":"16c5e4b627f873feee3fb53d94765767ba635b7f","datavalue":{"value":{"entity-type":"item","numeric-id":3274917,"id":"Q3274917"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$EF116D1A-FFC1-45C5-B0F0-34A2245CD9B6","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P223","hash":"484c591b53da865b53748dcabae6bebb7d7bb111","datavalue":{"value":{"entity-type":"item","numeric-id":3277327,"id":"Q3277327"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$3E5BABEA-6CEF-45D0-BD5F-A09207E1E2D0","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P223","hash":"0a98236d7640ac154af2c0ab5e696cd20ecefff2","datavalue":{"value":{"entity-type":"item","numeric-id":3271347,"id":"Q3271347"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$132BA4C6-3628-4C33-AC3E-018E2FF48714","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P223","hash":"e639aaa59db69cda31dfd660283c5da79c50f352","datavalue":{"value":{"entity-type":"item","numeric-id":3277310,"id":"Q3277310"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$C8A2F81A-86CA-4562-AF46-2172E0E89606","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P223","hash":"8a9a7e10e89b882542e7a00d3cef2d0e2e690f4c","datavalue":{"value":{"entity-type":"item","numeric-id":3282818,"id":"Q3282818"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$5D41BC12-9E8C-45FA-B58A-124E412BBDDB","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P223","hash":"a1f4e84a144d909cb16cd8055f827a846c17305b","datavalue":{"value":{"entity-type":"item","numeric-id":3292442,"id":"Q3292442"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","id":"Q1080289$C7D0A728-C3EB-4CB3-87C8-97768870ED99","rank":"normal"}],"P1643":[{"mainsnak":{"snaktype":"value","property":"P1643","hash":"eb49a45577a4dcd747744720453dbeb13e3feb1f","datavalue":{"value":{"entity-type":"item","numeric-id":1080290,"id":"Q1080290"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","qualifiers":{"P1659":[{"snaktype":"value","property":"P1659","hash":"54f3115fedcdd24d398d1a4fe0a81331f0209532","datavalue":{"value":{"amount":"+0.8491787910461426","unit":"1"},"type":"quantity"},"datatype":"quantity"}],"P1660":[{"snaktype":"value","property":"P1660","hash":"a327a09ea0305e98d5cf33bd4036320e19f2aed0","datavalue":{"value":{"entity-type":"item","numeric-id":6821328,"id":"Q6821328"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P1659","P1660"],"id":"Q1080289$66BFACDF-F7BB-4137-BBDF-9CB93668ABB3","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1643","hash":"490962b8d8a4c4c8cd35270c3b5e89109a857166","datavalue":{"value":{"entity-type":"item","numeric-id":5573323,"id":"Q5573323"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","qualifiers":{"P1659":[{"snaktype":"value","property":"P1659","hash":"cc95f1f70f5c3a27f170c9db6f3693c77b235477","datavalue":{"value":{"amount":"+0.711847722530365","unit":"1"},"type":"quantity"},"datatype":"quantity"}],"P1660":[{"snaktype":"value","property":"P1660","hash":"a327a09ea0305e98d5cf33bd4036320e19f2aed0","datavalue":{"value":{"entity-type":"item","numeric-id":6821328,"id":"Q6821328"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P1659","P1660"],"id":"Q1080289$3546C7D9-5D23-46CD-BEB4-A78EACDAB8ED","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1643","hash":"b8f8c977edcba282c612c3ebe94b0d0d408c0524","datavalue":{"value":{"entity-type":"item","numeric-id":1284989,"id":"Q1284989"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","qualifiers":{"P1659":[{"snaktype":"value","property":"P1659","hash":"d00f9458ebbd38d268335b643ac32bc3d626eaf0","datavalue":{"value":{"amount":"+0.6958962082862854","unit":"1"},"type":"quantity"},"datatype":"quantity"}],"P1660":[{"snaktype":"value","property":"P1660","hash":"a327a09ea0305e98d5cf33bd4036320e19f2aed0","datavalue":{"value":{"entity-type":"item","numeric-id":6821328,"id":"Q6821328"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P1659","P1660"],"id":"Q1080289$78A1029B-2D3C-42B6-930A-E1B8A5AF2E44","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1643","hash":"4e37cd8d88c990913a22555fba35c0575f8c1dd6","datavalue":{"value":{"entity-type":"item","numeric-id":5960960,"id":"Q5960960"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","qualifiers":{"P1659":[{"snaktype":"value","property":"P1659","hash":"27547c5824d38049b6e9b796c0bbf1042da6bd65","datavalue":{"value":{"amount":"+0.6865946650505066","unit":"1"},"type":"quantity"},"datatype":"quantity"}],"P1660":[{"snaktype":"value","property":"P1660","hash":"a327a09ea0305e98d5cf33bd4036320e19f2aed0","datavalue":{"value":{"entity-type":"item","numeric-id":6821328,"id":"Q6821328"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P1659","P1660"],"id":"Q1080289$E330702A-F859-4DA3-8CF3-32642BAC339B","rank":"normal"},{"mainsnak":{"snaktype":"value","property":"P1643","hash":"03998244924438c706dff2ec0d837c3f531f0491","datavalue":{"value":{"entity-type":"item","numeric-id":2499997,"id":"Q2499997"},"type":"wikibase-entityid"},"datatype":"wikibase-item"},"type":"statement","qualifiers":{"P1659":[{"snaktype":"value","property":"P1659","hash":"351aca65e6338962c8bd1870899d610793ac658c","datavalue":{"value":{"amount":"+0.685984194278717","unit":"1"},"type":"quantity"},"datatype":"quantity"}],"P1660":[{"snaktype":"value","property":"P1660","hash":"a327a09ea0305e98d5cf33bd4036320e19f2aed0","datavalue":{"value":{"entity-type":"item","numeric-id":6821328,"id":"Q6821328"},"type":"wikibase-entityid"},"datatype":"wikibase-item"}]},"qualifiers-order":["P1659","P1660"],"id":"Q1080289$E56BBA34-4879-4C35-8F9A-08EC5311BBA1","rank":"normal"}]},"sitelinks":{"mardi":{"site":"mardi","title":"Fluids with highly directional attractive forces. I. Statistical thermodynamics","badges":[],"url":"https://portal.mardi4nfdi.de/wiki/Fluids_with_highly_directional_attractive_forces._I._Statistical_thermodynamics"}}}}}