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Loewner} [Math. Z. 63, 338-340 (1955; Zbl 0068.250)] has shown that every non-singular totally positive matrix of finite order can be reached from the identity by forward solutions of the control equation \\(dR/dt=C(t)R\\), when C(t) varies in the class of Jacobi matrices with non- negative off-diagonal entries. We give a probabilistic solution of this equation by associating with it a finite-state non-stationary birth-and- death process and using the Feynman-Kac formula. This yields a probabilistic representation of non-singular totally positive matrices in terms of random evolutions.    We then extend the representation to compound matrices by making use of a multi-particle system due to \\textit{R. P. Feynman} [Phys. Rev., II. Ser. 76, 749-759 (1949; Zbl 0037.124), ibid. 76, 769-789 (1949; Zbl 0038.133)] and \\textit{S. Karlin} and \\textit{J. McGregor} [Pac. J. Math. 9, 1141-1164 (1959; Zbl 0092.345)].    As applications, we obtain both the Jacobi-Liouville formula and the inequality of \\textit{F. R. Gantmacher} and \\textit{M. G. Krein} [Oszillationsmatrizen, Oszillationskerne und kleine Schwingungen mechanischer Systeme. Akademie-Verlag (1964)] for the principal minors of totally positive matrices by simple probabilistic 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