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From the Gibbs equation and integrability condition for the Helmholtz function, one can calculate the terms in the thermodynamic pressure and internal energy which are of order \\((\\zeta - \\zeta_ 0)\\sigma^ 2\\), with \\(\\zeta_ 0\\) the equilibrium \\(\\zeta\\) and \\(\\sigma\\) the non-zero off-diagonal component of \\(\\sigma^{\\dag}_{ij}\\). Into these terms are substituted steady-state asymptotic solutions at high shear-rate, C, of the thermodynamic phenomenological rate equations. The steady-state solution exhibits bifurcation, and some of the possible steady states, with \\(\\zeta -\\zeta_ 0<0\\), predicts the \\(O(C^{3/2})\\) nonanalyticity seen in molecular dynamics simulations by \\textit{H. J. M. Hanley} and \\textit{D. J. Evans} [J. Chem. Phys. 76, 3226 ff (1982)]. The predicted signs and orders-of-magnitude also agree with computer studies. 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