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Let \\(R_{\\pi}=\\{\\alpha \\in {\\mathbb{Q}}[\\omega]|\\nu_{\\rho}(\\alpha)\\geq 0\\) whenever \\(\\rho\\) is a prime ideal divisor of \\(| G|_{\\pi}{\\mathbb{Z}}[\\omega]\\}\\). Then \\(R_{\\pi}\\) is a principal ideal domain. Definition: A subset \\(B_{\\pi}\\) of Irr(G) such that \\(| G|^{-1}\\sum_{\\chi \\in B_{\\pi}}\\sum_{g\\in G}\\chi (1)\\chi (g^{-1})g\\) is a primitive idempotent of \\(Z(R_{\\pi}G)\\) is called a \\(\\pi\\)-block. If G is a \\(\\pi\\)- group then G has only one \\(\\pi\\)-block. If G is a \\(\\pi'\\)-group then each \\(\\pi\\)-block of G contains exactly one irreducible character of G.    The main aim of this paper is to prove the second main Theorem for \\(\\pi\\)- blocks: Th. 6. Let \\(\\pi\\subseteq \\pi(G)\\), let B be a \\(\\pi\\)-block of G, x be a \\(\\pi\\)-element of G. Then there is a uniquely determined union of \\(\\pi\\)-blocks of \\(C_ G(x)\\), say B(x) such that (i) whenever \\(y,z\\in C_ G(x)_{\\pi'}\\),  \\[  \\sum_{\\chi \\in B}\\chi(x^{-1}y^{-1})\\chi(xz)= \\sum_{\\mu \\in B(x)}\\mu (y^{-1})\\mu(z).  \\]  (ii) Whenever \\(\\chi'\\in B\\) and y is a \\(\\pi\\)-regular element of \\(C_ G(x)\\) we have  \\[  \\chi'(xy)=\\sum_{\\mu \\in B(x)}<\\chi'_{C_ G(x)},\\mu >\\mu(xy).  \\]  (iii) Whenever \\(\\chi\\in Irr(G)\\) has the property that there are complex numbers \\(\\{c_{\\mu}|\\mu\\in B(x)\\}\\) such that \\(\\chi(xy)=\\sum_{\\mu \\in B(x)}c_{\\mu}\\mu(xy)\\) for each \\(\\pi\\)-regular \\(y\\in C_ G(x)\\) then either \\(\\chi\\in B\\) or \\(\\chi\\) vanishes on \\(S^ 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