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In doing this, the primeness of A (in the sense of non-commutative ring theory) is considered to be a fundamental device and exploited in several ways. It is shown that the extended centroid of a prime \\(C^ *\\)-algebra A is trivial and thus the canonical epimorphism between \\(M(A)\\otimes M(A)^{op}(M(A)^{op}\\) denoting the opposite algebra of M(A)) and El(A), the algebra of all elementary operators on A, is an isomorphism. This extends results of \\textit{C. K. Fong} and \\textit{A. R. Sourour} [Can. J. Math. 31, 845-857 (1979; Zbl 0408.47028)] for the algebra B(H) and the Calkin algebra C(H); in particular, their use of Voiculescu's non- commutative Weyl-von Neumann theorem is replaced by much more elementary techniques. Applications are characterizations of hermitian-preserving and of completely positive elementary operators on prime \\(C^ *\\)- algebras as well as a description of their extreme points in the corresponding convex cone [extending results by \\textit{M.-D. Choi}, Linear Alg. Appl. 10, 285-290 (1975; Zbl 0327.15018) and others].    Another section of the paper deals with the spectral theory of elementary operators where a complete description is given for the various parts \\(\\sigma _{\\ell}(S)\\), AP\\(\\sigma\\) (S), etc. and for \\(\\sigma\\) (S) in terms of the joint spectrum in the sense of R. E. Harte; ultraweak denseness of the range of S (in the case of a \\(W^ *\\)-algebra) is also discussed. These results generalize many of the results on the spectra of S known so far for B(H), C(H), or other special cases only, mainly established by Fialkow in a series of papers. Using the primeness, however, opens a much more direct and simplified approach.    The second part of the paper which will appear in the Glasgow Math. 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