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In earlier works the author has introduced the concept of S-expansions. It is shown that Minkowski's diagonal continued fraction is a special example of an S-expansion, and supported by knowing this fact, some metrical results on distribution properties of some sequences connected with Minkowski's diagonal expansion are shown.    As an example: Let x be an irrational number and let \\((a_ k)_{k\\geq 0}\\) be the sequence of the diagonal continued fraction-partial quotients of x. Then  \\[  \\lim_{N\\to \\infty}(1/N)\\quad \\#\\{j\\leq N;\\quad a_ j=1\\}=2(\\log (\\sqrt{2}-1)+\\sqrt{2}-1/2)=0.0656...  \\]  almost everywhere.    Finally an algorithm is given to gain Minkowski's diagonal continued fraction expansion of x from the regular continued fraction expansion of 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