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The paper is concerned with proving upper and lower pointwise estimates of the heat kernel \\(p_ t\\) in the case when \\(G\\) is a Lie group of polynomial growth or \\(G\\) is a unimodular compact extension of a solvable Lie group of exponential growth. Some of the results were obtained previously by \\textit{N. Varopoulos} [J. Funct. Anal. 76, 346-410 (1988; Zbl 0634.22008)] and \\textit{L. Saloff-Coste} [Ark. Mat. 28, 315-331 (1990; Zbl 0715.43009)] and in those cases new proofs of the results were supplied, while some others are new. 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