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Snow is described as a special kind of multiphase mixture. That means that spacial balances are established for each component, interfacial balances are not introduced. Besides the balance equations of mass, momentum, angular momentum and energy, an additional one must be formulated to take into account the interaction of the phases, here called the balance of equilibrated force that refers to the volume fraction of the component as essential kinematical variable. The second law of thermodynamics is represented by the Clausius-Duhem inequality the mixture with the entropy flux being equal to the heat flux over temperature. As usually in multiphase theories, the constitutive quantities of each constituent depend on variables of the same constituent, only the interaction terms depend on the variables of all components. On this base the residual entropy unequality is analysed at the equilibrium state and in the neighbourhood of equilibrium. 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