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Here \\(g(M)\\) is the set of isomorphism classes of finitely generated \\(R\\)- modules \\(N\\) locally isomorphic to \\(M\\). This works for the case \\(\\text{rank}(M)\\neq 2\\), while if \\(\\text{rank}(M)=2\\) then \\(g(M)\\) is replaced by a suitable quotient of \\(g(M)\\). The structure reduces to the usual group structure on \\(\\text{Pic}(R)\\) in case \\(M=R\\). The group \\(g(M)\\) is related to \\(\\tilde K_ 0(R)\\) via an exact sequence.   The following are some of the results obtained as an application: (1) If \\(R\\) is a regular affine domain over an algebraically closed field of characteristic zero then direct-sum cancellation holds for torsion-free \\(R\\)-modules. (2) Let \\(R=k[X,Y]\\), where \\(k\\) is a field. If \\(\\text{char}(k)>0\\) or \\(k\\) is not \\(n\\)-th root closed for some \\(n\\) then direct-sum cancellation for torsion-free \\(R\\)-modules does not hold. 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