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Though it is well-known that conclusions about the asymptotic behaviour of the process may be drawn from spectral information, it turns out that \\(W(T)\\) can be used to obtain strong results about the finite stage of the processes, and error estimates for Chebyshev semi-iterative methods in terms of the numerical radius are obtained.   The author obtains also some results about the location of \\(W(T)\\) for Toeplitz matrices. Finally, a new approach to the definition of optimal parameter \\(\\omega\\) in SOR methods studied recently by \\textit{G. H. Golub} and \\textit{J. E. de Pillis} [Towards an effective two-parameters SOR- method. In: Iterative methods for large linear systems (D. R. Kincaid and L. J. Hayes, Eds.), Academic Press, Boston, 107-115 (1989)] is proposed. 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