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A function \\(f\\) of the form \\(f(z)= \\int(t-z)^{-1} d\\mu(t)\\), where \\(\\mu\\) is a positive measure of compact support in \\(\\mathbb{R}\\) is a Markov function; if \\(\\text{supp} \\mu \\subseteq(-1,1)\\) then \\(f\\in H^2(V)\\). The paper is concerned with the uniqueness or non-uniqueness of best approximation to Markov functions \\(f\\in H^2(V)\\) by functions of \\({\\mathcal R}^1_{n-1,n}\\) for \\(n\\in\\mathbb{N}\\), and it presents two main results. Theorem 4: There exist Borel measures \\(\\mu\\) with countable \\(\\text{supp} \\mu \\subseteq(-1,1)\\) such that for each odd \\(n\\in\\mathbb{N}\\) the best approximation in \\(H^2(V)\\) to \\(f\\) from \\({\\mathcal R}^1_{n-1, n}\\) is not unique. Theorem 5: Let \\(n_0\\in \\mathbb{N}\\) be odd. There exists a Borel measure \\(\\mu\\) such that \\(\\text{supp} \\mu\\) is a closed subinterval of \\((-1,1)\\), \\(\\mu\\) has a positive smooth density function on \\(\\text{supp} \\mu\\), and for each odd \\(n\\leq n_0\\) the best approximation in \\(H^2(V)\\) to \\(f\\) from \\({\\mathcal R}^1_{n-1,n}\\) is not unique. The measure \\(\\mu\\) constructed for Theorem 5 belongs to the Szeg\u00f6 class and it follows from a result of the same authors (Asymptotic uniqueness of best rational approximants of given degree to Markov functions in \\({\\mathcal L}^2\\) of the circle (to appear) stated here as Theorem 3, that best approximants to \\(f\\) from \\({\\mathcal R}^1_{n-1,n}\\) are unique for all but a finite set of 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