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Math. 122, No. 2, 309-340 (1995; Zbl 0841.14037), \\textit{A. Buium} introduced an arithmetic analogue of derivations, called \\(\\pi\\)-derivations; this concept was used to prove a series of arithmetic analogues of results about algebraic differential equations. The question arises of how ``natural'' these \\(\\pi\\)-derivation operators are and what other choices one has in defining arithmetic analogues of ``usual'' derivations. The present note is an attempt to answer this question: We will introduce an a priori quite general notion of jet operator on a ring and prove that any such operator on a local domain of characteristic zero is ``equivalent'' to one of the following: a difference operator, a derivation operator, a \\(\\pi\\)-difference operator, or a \\(\\pi\\)-derivation operator in the sense of the author's paper cited above. The first three kinds of operators are always trivial on the rational integers; so one is left with the fourth kind, i.e., with the \\(\\pi\\)-derivations of the paper cited above, as the ``only'' possibility, within our paradigm, for an arithmetic analogue of usual 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