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The quotient \\(g/f\\) is called badly approximable if all the partial quotients of the continued fraction of \\(g/f\\) have degree 1. For a given \\(f\\), the order of the set \\(\\{g\\in F[x] \\mid \\text{deg } g<\\text{deg } f\\) and \\(g/f\\) is badly approximable\\} is called the orthogonal multiplicity of \\(f\\). In this paper the author gives a characterization of those polynomials with orthogonal multiplicity one: when \\(| F| \\neq 2\\) then \\(f\\) has orthogonal multiplicity one if and only if \\(f=1\\), and when \\(| F| =2\\) then \\(f\\) has orthogonal multiplicity one if and only if \\(f=X^{e_{0}}(X+1)^{e_{1}}\\) where \\(\\binom{e_{0}+e_{1}}{e_{1}}\\equiv 1\\bmod 2\\). This result generalises two results of \\textit{H. Niederreiter} [Monatsh. Math. 103, 269-288 (1987; Zbl 0624.12011)]. The author also proves that if \\(| F| \\geq d(d+1)/2\\) where \\(d=\\text{deg } f\\), then \\(f\\) has positive orthogonal 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