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The FRT-dual of \\(A\\) is the Hopf subalgebra \\(U(A)\\) of the Hopf dual generated by the l-functionals \\(r(. \\otimes a)\\) and \\(\\overline r(a \\otimes .)\\), \\(a \\in A\\), where \\(\\overline r\\) denotes the convolution inverse of \\(r\\). By results of \\textit{S. Majid} [Foundations of quantum group theory, Cambridge: Cambridge Univ. Press (1995; Zbl 0857.17009)] and \\textit{T. J. Hodges} [J. Algebra 192, 303-325 (1997; Zbl 0879.17003)] there exist an injective algebra map \\(\\iota: U(A \\bowtie A) \\to U(A) \\otimes U(A)\\) and a surjective Hopf algebra map \\(\\zeta: A^{\\text{op}} \\otimes U(A) \\to U(A \\bowtie A)\\); here, \\(A \\bowtie A\\) is the quantum double of \\((A, r)\\). This paper contributes to the study of these maps in the case where \\(A = \\mathbb C_q[G]\\) is the quantum coordinate algebra associated to a connected complex semisimple Lie group \\(G\\), and \\(0 \\neq q \\in \\mathbb C\\) is not a root of unity. 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For the classical groups, a certain choice of root vectors for \\(U_q(\\mathfrak g)\\) is expressed in terms of l-functions, which allows the author to give an explicit formula for their 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