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More specifically, under suitable assumptions it is shown (see Theorem 4.1) that for any orthonormal basis $(\\phi_j)_{j\\in J}$ in a Hilbert space $\\mathcal{G}$ and a.e. $\\lambda\\in\\mathbb{R}$ it holds \\[ xi(\\lambda)=\\sum_{j\\in J}\\lim_{\\epsilon\\downarrow0}\\pi^{-1}\\Big(\\mathrm{Im}\\big(\\log\\big(\\overline{M(\\lambda+i\\epsilon)}\\big)\\big)\\phi_j,\\phi_j\\Big)_\\mathcal{G} \\] and for any $z\\in\\rho(A)\\cap\\rho(B)$ the trace formula \\[ \\mathrm{tr}_{\\mathfrak{H}}\\big((B-zI_{\\mathfrak{H}})^{-(2k+1)}-(A-zI_{\\mathfrak{H}})^{-(2k+1)}\\big)=-(2k+1)\\int_{\\mathbb{R}}\\frac{\\xi(\\lambda)\\,\\mathrm{d}\\lambda}{(\\lambda-z)^{2k+2}} \\] is valid. The proof of the main result is based on the study of the logarithm of operator-valued Nevanlinna (or Herglotz) function from Section 3. 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