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There has been considerable effort devoted to construct units of the integral group ring over the past decades. Let \\(C_n=\\langle x\\rangle\\) be a cyclic group of finite order \\(n\\), then every element of \\(\\mathbb{Z}C_n\\) is the result of evaluating a polynomial \\(P(X)\\in\\mathbb{Z}[X]\\) of degree less than \\(n\\) at \\(x\\). When \\(P(x)\\in U(\\mathbb{Z}C_n)\\), \\(P(X)\\) is said to define a unit on order \\(n\\). \\textit{Z. Marciniak} and \\textit{S. K. Sehgal} [Lect. Notes Pure Appl. Math. 248, 279--286 (2006; Zbl 1110.16034)] proved that the only normalized (i.e., \\(P(1)=1\\)) irreducible polynomial of degree 2 defining units is \\(\\Phi_6(X)=X^2-X+1\\); for degree 3 Marciniak found \\(X^3+X^2-1\\) and \\(-X^3+X+1\\). Recently, the authors found all polynomials defining units on infinitely many orders [Math. Z. 283, No. 3--4, 1195--1200 (2016; Zbl 1356.16030)].  The main results of the present paper are as follows. A shift of \\(P(X)\\) is the polynomial obtained from \\(P\\) by cyclically permuting the coefficients. Let \\(U_{a,b}(X)= aX^4+bX^3+(1-2a-2b)X^2+bX+a\\). If \\(P(X)\\) is a normalized irreducible polynomial of degree 4 defining units on order \\(n\\geq5\\) then either (1) \\(n=5\\) and \\(P(X)\\) equals a shift of \\(U_{a,b}(X)\\) for some integers \\(a,\\,b\\); (2) \\(n=7\\) and \\(P(X)\\) equals either \\(X^4+X^3-1\\) or \\(-X^4+X+1\\); or (3) \\(n\\geq7\\) and \\(P(X)\\) equals \\(U_{a,b}(X)\\) for some integers \\(a,\\,b\\). Moreover, it is shown that if \\(n>5\\) then the number of irreducible normalized polynomials of degree 4 defining units on order \\(n\\) is finite, for \\(n\\leq10\\) all these are explicitly listed, for instance if \\(n=7\\) then these are \\(X^4+X^3-1\\), \\(-X^4+X+1\\) and the \\(U_{a,b}(X)\\) with \\((a,b)\\in\\{(1,0),(1,-1),(-1,2)\\}\\). For \\(n=11\\) the corresponding Diophantine equation for \\(a, b\\) seems too complicated to be 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