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But motivated by problems of model uncertainties in statistics, measures of risk, and superhedging in finance, sublinear expectations are extensively studied. In this paper, we obtain a type of large deviation principle under the sublinear expectation. This result is a new expression of the G\u00e4rtner-Ellis theorem under the sublinear expectations which is in the classical theory of large deviations. In addition, we introduce a new process under the sublinear expectations, that is, the \\(G\\)-Poisson process. We give an application of our result and obtain the rate function of the compound \\(G\\)-Poisson process in the upper bound of large deviations for capacities. 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