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A novel approach is explored for designing the e-recycling reverse logistics network (RLN) under uncertainty. The goal is to obtain a solution, i.e., increasing the storage capacity of the logistics node, to achieve optimal or near-optimal profit under the collection requirement set by the government and the investment from the enterprise. The approach comprises two parts: a matrix-based simulation model of RLN formed for the uncertainty of demand and reverse logistics collection which calculates the profit under a given candidate solution and simulated annealing (SA) algorithm that is tailored to generating solution using the output of RLN model. To increase the efficiency of the SA algorithm, network static analysis is proposed for getting the quantitative importance of each node in RLN, including the static network generation process and index design. 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