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A pseudocompact group is called \\textit{doubly extremal} if it is both \\(r\\)- and \\(s\\)-extremal. The starting point of this paper is the following conjecture which remains open: No nonmetrizable pseudocompact Abelian group is neither \\(r\\)- nor \\noindent\\(s\\)-extremal. The authors develop a technique of strengthening a pseudocompact group topology (by using homomorphisms in the circle group \\(\\mathbb{T}\\)) (Theorem 3.10). It is proved that the following classes of pseudocompact groups are neither \\(r\\)-extremal nor \\(s\\)-extremal: i) non-divisible connected pseudocompact Abelian groups (Theorem 4.5); ii) totally disconnected Abelian groups of uncountable weight (Corollary 5.8): iii) pseudocompact Abelian groups for which \\(\\omega < w(G)\\leq 2^{\\omega}\\) (here \\(w(G)\\) is the weight of \\(G\\)) (Theorem 5.10(a)). If in a pseudocompact Abelian group \\(G\\) of uncountable weight every closed subgroup is pseudocompact and \\(G\\) contains a nonmetrizable finitely generated subgroup, then \\(G\\) is not \\(s\\)-extremal (Theorem 6.9). It is proved that under Luzin's hypothesis \\([2^\\omega=2^{\\omega_1}]\\) if in a topological Abelian group \\(G\\) of uncountable weight every closed subgroup is pseudocompact, then \\(G\\) is not \\(s\\)-extremal (Theorem 6.10). Furthermore, it is proved that if \\(G\\) is a pseudocompact group, \\(w(G)>\\omega,\\) then: i) If every closed subgroup of \\(G\\) is pseudocompact, then \\(G\\) is not doubly extremal; ii) if \\(G\\) is countably compact or torsion-free, then \\(G\\) is not doubly extremal (Corollary 7.3). 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