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The author describes the course of the paper as follows:   ``In Section 2 we collect the necessary results on central extensions of topological groups and in Section 3 we provide some results on infinite-dimensional manifolds and Lie groups which are well-known in the finite-dimensional case. In Section 4 we explain how the setting for abstract, resp., topological groups has to be modified to deal with central extensions of Lie groups with smooth local sections. Section 5 is dedicated to the construction of the period homomorphism \\(\\text{per}_\\omega: \\pi_2 (G)\\to z\\). Section 6, which is the heart of the paper, contains the construction of a global group cocycle \\(f:G\\times G\\to Z\\) for simply connected groups \\(G\\) and any Lie algebra cocycle \\(\\omega\\), where \\(Z\\) can be defined as \\(z/ \\Pi_\\omega\\). The so defined group \\(Z\\) is a Lie group iff \\(\\Pi_\\omega\\) is discrete, so that we obtain a Lie group extension iff \\(\\Pi_\\omega\\) is discrete. In Section 7 we eventually put all pieces together to prove the exactness of (1). The central result of Section 8 is Theorem 8.8 which gives a version of the exact sequence (1) for central Lie group extensions with smooth global sections. Section 9 is a collection of examples displaying various aspects in the description of the group \\(\\text{Ext}_{\\text{Lie}} (G,Z)\\) by the exact sequence 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