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To characterize the rates of each such piecewise polynomial approximation we introduce a family of smoothness spaces (B-spaces) which can be viewed as an anisotropic variation of Besov spaces. We use the B-spaces to prove Jackson and Bernstein estimates and then characterize the piecewise polynomial approximation by interpolation. Our main estimate relates \\(n\\)-term rational approximation with piecewise polynomial approximation in \\(L_p(\\mathbb{R}^d)\\). This result enables us to obtain a direct estimate for \\(n\\)-term rational approximation in terms of a minimal B-norm (over all dyadic partitions). We also show that the Haar bases associated with anisotropic dyadic partitions of \\(\\mathbb{R}^d\\) can be successfully utilized for nonlinear approximation. 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