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The first one is a characterization of Besov spaces in terms of mollifications. The idea is based on the multifractal quantity  \\[ \\mu^\\lambda_{p,q}=\\biggl(\\sum_j 2^{j\\lambda q} \\biggl(\\sum_m \\mu(Q_{j,m})^p\\biggr)^{q/p}\\biggr)^{1/q} \\]  introduced for Radon measures \\(\\mu\\). Here \\(Q_{j,m}\\) denotes a standard dyadic cube. It is known that \\(\\mu\\in B^s_{p,q}({\\mathbb R}^n)\\), \\(s<0\\), iff \\(\\mu^\\lambda_{p,q}<\\infty\\) and \\(s=\\lambda+n(\\frac 1 p -1)\\). The aim of the paper is to extend this characterization to positive smoothnesses, \\(s>0\\). For this purpose, mollifications are used. The second aim is to study multifractal quantities for distributions. In particular, generalizations \\(\\lambda^f\\), \\(s_f\\), \\(f\\in {\\mathcal S}'({\\mathbb R}^n)\\), of the quantities \\(\\lambda_\\mu(\\frac 1 p)=\\sup\\{\\lambda:\\, \\mu^\\lambda_{p,q}<\\infty\\}\\) and \\(s_\\mu(\\frac 1 p)=\\sup\\{s: \\mu\\in B^s_{p,q}({\\mathbb R}^n)\\}\\) are considered. It is proven that \\(s_f(\\frac 1 p)= \\lambda^f(\\frac 1 p)+ n(\\frac 1 p - 1)\\) if \\(f\\) has compact 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