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Let \\(X\\) be a projective smooth complex surface, and \\(\\Delta\\), \\(c\\) be a divisor on \\(X\\) and an integer, respectively. If \\(L\\) is an ample line bundle on \\(X\\), let \\({\\mathcal M}_L (\\Delta,c)\\) be the moduli space of (Gieseker) \\(L\\)-semistable rank-two torsion-free sheaves \\(F\\) on \\(X\\) with \\(\\text{det} F\\cong {\\mathcal O}_X (\\Delta)\\) and \\(e_2(F)=c\\). If \\(c_1(L)\\) belongs to the complement of a certain set of walls in the ample cone, one can define certain classes in the cohomology of \\({\\mathcal M}_L (\\Delta,c)\\); intersection of these classes defines a so-called Donaldson polynomial of \\(X\\). If \\(p_g (X)>0\\) these polynomials do not depend on the choice of \\(L\\), if \\(p_g(X) =0\\) they depend only on the open chamber (in the complement of the walls) containing \\(c_1(L)\\):    If \\({\\mathcal C}\\) denotes the chamber, let \\(D^X_{\\Delta,c} ({\\mathcal C})\\) be the corresponding polynomial.    Assuming \\(p_g(X) =0\\), the question is: How does \\(D^X_{\\Delta,c} ({\\mathcal C})\\) vary when we change the chamber? It suffices to determine the difference \\(\\delta^X_{\\Delta,c} ({\\mathcal C}_+, {\\mathcal C}_-): =D^X_{\\Delta,c} ({\\mathcal C}_+) - D^X_{\\Delta,c} ({\\mathcal C}_-)\\) for chambers separated by a single wall. If \\({\\mathcal M}_+\\), \\({\\mathcal M}_-\\) are the corresponding moduli spaces, the authors describe how to obtain \\({\\mathcal M}_+\\) from \\({\\mathcal M}_-\\) by a sequence of blow-ups and blow-downs (flips); this result holds with no restriction on \\(p_g(X)\\). The authors analyze in greater detail the case when \\(X\\) is rational with \\(-K_X\\) effective, and they obtain formulae for some of the differences \\(\\delta^X_{\\Delta,c} ({\\mathcal C}_+, {\\mathcal 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