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Assume that the positivity of transition probability \\(p(x,y)\\) implies \\([x,y]\\in E.\\) Then the limiting variable \\(X_{\\infty}\\) takes value in the Martin boundary \\(\\Omega\\) of the chain X with law \\(\\nu_x\\) under \\( P_x\\). The following problem is studied: When does \\(\\{\\nu_x:x\\in V\\}\\) uniquely determine \\(p(x,y)\\)? The main result is: Under the additional regularity assumption of supp\\((\\nu_x)=\\Omega\\) for any \\( x\\in V\\), the family of limiting distributions \\(\\{\\nu_x:\\) \\(x\\in V\\}\\) uniquely determines transition probabilites of X iff all vertices are cutvertices. Applications on random walks on free products of finite groups are also discussed. 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