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Let \\(X\\) be a normal variety with at worst log canonical singularities and \\(D\\) be an effective \\(\\mathbb{Q}\\)-Cartier divisor. The log canonical threshold of \\(D\\) along a subvariety \\(Z\\) of \\(X\\) is defined by \\[\\mathrm{lct}_{Z}(X,D) := \\mathrm{sup} \\{ \\lambda \\in \\mathbb{Q} \\, : \\, (X, \\lambda D) \\text{ is log canonical along } Z\\}.\\] If \\(Z=X\\), then we write \\(\\mathrm{lct}_{Z}(X,D) = \\mathrm{lct}(X,D)\\). Using the definition of the log canonical threshold we can define the global log canonical threshold of \\(X\\) as \\[ \\mathrm{glct}(X) :=\\mathrm{inf} \\bigg\\{ \\mathrm{lct} (X,D) \\, | \\, D \\text{ is an effective } \\mathbb{Q} \\text{-Cartier divisor on } X \\]  \\[ \\text{ which is } \\mathbb{Q} \\text{-linearly equivalent to } -K_{X} \\bigg\\}. \\] The global log canonical threshold is an algebraic counterpart of Tian's \\(\\alpha\\)-invariant which is used to study the existence of K\u00e4hler-Einstein metric for an arbitrary polarized pair \\((X,L)\\), where \\(X\\) is a smooth variety and \\(L\\) is an ample divisor on it. In this setup, one can define the global log canonical threshold for a \\(\\mathbb{Q}\\)-Cartier divisor \\(\\mathcal{L}\\) on a normal variety \\(X\\) with at worst log canonical singularities, namely \\[ \\mathrm{glct}(X,\\mathcal{L}) :=\\mathrm{inf} \\bigg\\{\\mathrm{lct} (X,D) \\, | \\, D \\text{ is an effective } \\mathbb{Q} \\text{-Cartier divisor on } X \\]  \\[ \\text{ which is } \\mathbb{Q} \\text{-linearly equivalent to } \\mathcal{L} \\bigg\\}. \\]  In the present paper the authors study the global log canonical thresholds for Burniat surfaces \\(X\\) with \\(K_{X}^{2} = 6\\) via their canonical divisors. Such surfaces are minimal surfaces of general type with \\(p_{g} = 0\\) constructed as bidouble covers of \\(\\mathbb{P}^{2}\\). In the first part of the paper, the authors consider a polarized pair \\((X, 2K_{X})\\). The bicanonical map \\(\\phi\\) of \\(X\\) has an image that is a del-Pezzo surface \\(\\Sigma\\) of degree \\(6\\) in \\(\\mathbb{P}^{6}\\). In this scenario, the authors show that the global log canonical threshold of the polarized pair \\((X, K_{X})\\) is \\(\\frac{1}{2}\\), and \\[\\mathrm{glct}(X, 2K_{X}) =\\mathrm{lct}(X,D) = \\frac{1}{4}\\] for some divisor \\(D \\in |2K_{X}|\\).  The second main result of the paper can be formulated as follows.  Theorem. Let \\(X\\) be a Burniat surface with \\(K_{X}^{2} = 6\\) and let \\(m\\) be a positive even integer. Then any divisor \\(D \\in |mK_{X}|\\) such that \\(\\mathrm{glct}(X, K_{X}) = \\mathrm{lct}(X, \\frac{1}{m}D)\\) is invariant under the \\(\\mathbb{Z}_{2}^{2}\\)-action associated to the bicanonical map \\(\\phi\\) of 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