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In [\\textit{N. Gigli}, Nonsmooth differential geometry -- an approach tailored for spaces with Ricci curvature bounded from below. Providence, RI: American Mathematical Society (AMS) (2018; Zbl 1404.53056)] a second-order calculus on \\(\\mathsf{RCD}\\) spaces has been developed, in particular defining the space \\(H^{2,2}\\) and a notion of Hessian for a function \\(f\\in H^{2,2}\\).  The present paper deals with a second-order differentiation formula for \\(H^{2,2}\\) functions along geodesics on \\(\\mathsf{RCD}^{*}(K,N)\\) spaces. More precisely, in the main result of the article it is established that \\[\\frac{\\mathrm{d}^2}{\\mathrm{d}t^2}\\int f\\, \\mathrm{d}\\mu_t = \\int \\mathrm{Hess}(f)(\\nabla \\phi_t,\\nabla \\phi_t)\\, \\mathrm{d}\\mu_t, \\qquad \\textrm{for every} \\ \\ t\\in [0,1],\\] where \\(f\\in H^{2,2}\\), \\(\\mu_t\\) is a 2-Wasserstein geodesic and \\(\\phi_t\\) is a function such that \\(-(s-t)\\phi_t\\) is a Kantorovich potential from \\(\\mu_t\\) to \\(\\mu_s\\), \\(s,t\\in [0,1]\\).  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