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In this paper, the author proves that a similar representation is also valid for a polyorthogonal polynomial if the power moments of the measures \\(\\mu _j\\) are known. In this respect, notice that polyorthogonal polynomials (named also as \\lq multiple orthogonal polynomial\\rq) satisfy non-standard orthogonality relations and naturally arise as the common denominator of the Pad\u00e9 approximations for the system of Markov functions. Here, the orthogonality relations are distributed among several measures \\(\\mu _1,...,\\mu _k\\).  Moreover, the author considers the concept of orthogonality in a broader sense, when the orthogonal polynomial is defined for an arbitrary sequence \\(\\{s_i\\}\\), which is not bound by any restrictions. In this general situation, necessary and sufficient conditions for the existence and uniqueness of a polyorthogonal polynomial are found, under which it can be represented in determinant form similar to one above. As a consequence, similar representations are obtained for the residual function, the numerator, and the denominator of the corresponding Pad\u00e9 approximations, complementing this way well-known results in the theory of polyorthogonal polynomials and Pad\u00e9 approximations.  A fundamental role is played by new concepts which are introduced in the paper, namely, an admissible index and an almost perfect system of 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