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The first isomonodromic system \\[\\, \\frac{d Y}{d z}=\\left(\\Lambda(u) + \\frac{A(u)}{z}\\right)\\,Y, \\quad \\Lambda(u)=\\mathrm{diag} (u_1, \\ldots, u_n) \\,\\] has a Fuchsian singularity at \\(z=0\\) and an irregular singularity at \\(z=\\infty\\) of Poincar\u00e9 rank 1, while the second isomonodromic system \\[\\, \\frac{d \\Psi}{d \\lambda}=\\left(\\sum_{k=1}^{\\infty} \\frac{B_k(u)}{\\lambda-u_k}\\right)\\,\\Psi, \\quad B_k=-E_k (A(u)+I) \\,\\] is a Fuchsian system. Here, \\(E_k\\) is a matrix, whose entries are zero, except for \\((E_k)_{kk}=1\\) and the parameters of deformation \\(u=(u_1, \\ldots, u_n)\\) vary in a polydisc containing a locus of coalescence points such that \\(u_i=u_j\\) for some \\(1 \\leq i \\neq j \\leq n\\). This result is based on the construction of such selected \\(\\vec{\\Psi}_k(\\lambda, u)\\) and singular \\(\\vec{\\Psi}_k^{(sing)}(\\lambda, u),\\,k=1,\\ldots, n\\) vector solutions of the Fuchsian Pfaffian system, that allows the author to introduce isomonodromic connection coefficients. With this construction the author extends the results of \\textit{W. Balser} et al. [SIAM J. Math. Anal. 12, 691--721 (1981; Zbl 0468.34024)] to the case of isomonodromic deformations with coalescing Fuchsian singularities \\(u_1, \\ldots, u_n\\). Utilizing the obtained relation the author proves in terms of the isomonodromic Laplace transform the main results in [\\textit{G. Cotti} et al., Duke Math. 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