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A locally convex space \\(E\\) satisfies that \\((E,\\sigma(E,E'))\\) is Eberlein-Grothendieck if and only if its weak* dual \\((E',\\sigma(E',E))\\) is a countable union of compact sets (that is, it is \\(\\sigma\\)-compact). A locally convex space \\(E\\) satisfies that \\((E,\\sigma(E,E'))\\) is linearly Eberlein-Grothendieck if and only if there is a \\(\\sigma(E,E')\\)-compact subset \\(K\\) of \\(E'\\) such that the span of \\(K\\) coincides with \\(E'\\). The main result of the paper asserts that a barrelled locally convex space \\(E\\) satisfies that \\((E,\\sigma(E,E'))\\) is Eberlein-Grothendieck (respectively linearly Eberlein-Grothendieck) if and only if \\(E\\) is metrizable (respectively normable). As an application, several results about spaces of continuous functions with the pointwise topology are presented. 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