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A \\textit{Leibniz \\({\\mathfrak g}\\)-bimodule} is a vector space \\(M\\) with left and right operations by \\({\\mathfrak g}\\) satisfying for all \\(x,y\\in{\\mathfrak g}\\) and all \\(m\\in M\\) \\begin{itemize} \\item[(a)] \\(m\\cdot[x,y]=(m\\cdot x)\\cdot y - (m\\cdot y)\\cdot x\\), \\item[(b)] \\(x\\cdot(m\\cdot y) = (x\\cdot m)\\cdot y)-[x,y]\\cdot m\\), \\item[(c)] \\(x\\cdot(y\\cdot m) = [x,y]\\cdot m - (x\\cdot m)\\cdot y\\). \\end{itemize} For a given right \\({\\mathfrak g}_{\\mathrm{Lie}}\\)-module \\(M\\), there are two ways of obtaining a Leibniz \\({\\mathfrak g}\\)-bimodule, namely the antisymmetric version \\(M^a\\) where \\(x\\cdot m=0\\), and the symmetric version \\(M^s\\), where \\(x\\cdot m=-m\\cdot x\\). These notions have been invented and studied thoroughly by Loday and Pirashvili.  In particular, in [\\textit{J.-L. Loday} and \\textit{T. Pirashvili}, J. Algebra 181, No. 2, 414--425 (1996; Zbl 0855.17018)], they study the category of (finite dimensional) bimodules over a (finite dimensional complex) simple Lie algebra, viewed as a Leibniz algebra. The main result has been adapted to (finite dimensional complex) simple Leibniz algebras in [\\textit{J. Mugni\u00e9ry} and the reviewer, J. Pure Appl. Algebra 225, No. 6, Article ID 106637, 16 p. (2021; Zbl 1477.17031)]. It emphasized the role of classes  \\[ [{\\mathcal E}_l^{\\mathfrak g}(N)]\\,\\,\\in\\,\\,\\mathrm{Ext}_{UL({\\mathfrak g})}^1(N^s, (N\\otimes {\\mathfrak g}^{\\downarrow})^a), \\] and  \\[ [{\\mathcal E}_r^{\\mathfrak g}(N)]\\,\\,\\in\\,\\,\\mathrm{Ext}_{UL({\\mathfrak g})}^1( \\mathrm{Hom}( {\\mathfrak g}^{\\downarrow},N)^s,N^a). \\] Here the functor \\(M\\mapsto M^{\\downarrow}\\) is the restriction functor, sending a Leibniz \\({\\mathfrak g}\\)-bimodule \\(M\\) to the underlying right \\({\\mathfrak g}_{\\mathrm{Lie}}\\)-module \\(M^{\\downarrow}\\).   The present article studies in detail these classes and puts them into a conceptual framework, namely the author shows that the two classes induce distinguished triangles in the derived category of right \\({\\mathfrak g}_{\\mathrm{Lie}}\\)-modules. Setting up the framework of the study, the author constructs with all necessary details the left and right adjoint functors of the functors \\(N\\mapsto N^s\\) and \\(N\\mapsto N^a\\), as well as their derived functors (constructing explicit resolutions). An interesting point in these constructions is notably the role of the Kurdiani involution (acting as \\(r_x\\mapsto -r_x\\) and \\(l_x\\mapsto r_x+l_x\\) in the universal enveloping algebra \\(UL({\\mathfrak g})\\) constructed by Loday-Pirashvili) and its use in duality. In the end of the article, it is shown how to apply these results in order to compute extensions for a general Leibniz algebra, extending the results of Loday-Pirashvili and 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