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For any group \\(G,\\) let \\(\\mathrm{Cent}(G)\\) denote the set of the centralizers of \\(G\\). Then \\(G\\) is called a \\(\\mathcal C_n\\)-group if \\(|\\mathrm{Cent}(G)|=n.\\) The author proves that if \\(G\\) is a non-abelian \\(\\mathcal C_n\\)-group, then \\(|G/Z(G)|\\leq (n-2)^2\\) if \\(n\\leq 12,\\) \\(|G/Z(G)|\\leq 2(n-4)^{\\log_2(n-4)}\\) otherwise, improving an earlier result by Zarrin. Recall that an F-group is a group in which every non-central element centralizer contains no other element centralizer. Among other results, the author proves that if \\(G\\) is non-abelian F-group, then \\(\\gcd(|\\mathrm{Cent}(G)|-2, |G/Z(G)|)\\neq 1.\\) If \\(G\\) is an F-group, then \\(\\mathrm{Cent}(G)\\geq |G|/2\\) if and only if \\(G\\cong A_4,\\) an extraspecial 2-group or a Frobenius group with abelian kernel and complement of order 2. 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