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The authors show that the Nekrasov-Okounkov partition function of this gauge theory provides an explicit combinatorial expression and a Fredholm determinant formula for the tau-function describing isomonodromic deformations of \\(\\mathrm{SL}_2\\) flat connections on the one-punctured torus. This is achieved by reformulating the Riemann-Hilbert problem associated to the latter in terms of chiral conformal blocks of a free-fermionic algebra. This viewpoint provides the exact solution of the renormalization group flow of the \\(\\mathrm{SU}(2)\\; \\mathcal{N}=2^*\\) theory on a self-dual-background and, in the Seiberg-Witten limit, an elegant relation between the IR and UV gauge couplings.   The paper is organized as follows. In Section 2 the authors recall  known results on the two-sphere. 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