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This principle proves that if \\(\\frac{\\partial ^{2}f}{\\partial x^{2}}>0\\) at a minimizer \\(x^{\\ast }\\) (regular minimum point), the sign of \\(\\frac{\\partial x^{\\ast }}{\\partial p_{j}}\\) is the opposite of that of \\(\\frac{\\partial ^{2}f}{\\partial x\\partial p_{j}}\\) at \\(x^{\\ast }\\) and that of \\(\\Delta x^{\\ast }\\) is the opposite of that of \\(\\frac{\\partial ^{2}f}{\\partial x\\partial p_{j}}\\Delta p_{j}\\) at \\(x^{\\ast }\\). The author illustrates this principle with examples in economics and mechanics. He then considers chemical reaction equilibrium problems which may be written as minimization ones for the Gibbs energy \\(G\\): \\(\\min_{\\xi }G(\\xi ;p)\\) where \\(\\xi \\) denotes the vector of dimension \\(R\\) of reaction extents and \\(p\\) that of parameters. In the case of a single reaction, the author describes the parameters to be considered and the applicability of Le Ch\u00e2telier principle. In the case of multiple variables, the author considers a chemically reacting system in an ideal solution phase at specified temperature and pressure. He proves that for every feasible point \\(\\mathbf{n}^{0}\\) satisfying the mass conservation and non-negativity constraints, then \\(\\sum_{j=1}^{R}\\sum_{k=1}^{R}\\frac{\\partial ^{2}(G/RT)}{\\partial \\xi_{j}\\partial \\xi _{k}}\\delta \\xi _{j}\\delta \\xi _{k}>0\\), where \\(n_{i}=\\mathbf{n}_{i}^{0}+\\sum_{j=1}^{R}\\nu _{ij}\\xi _{j}\\), for stoichiometric coefficients \\(\\nu _{ij}\\). He finally discusses the influence of finite variations of the 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