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A set \\(S\\) of vertices of the graph \\(G\\) is a doubly resolving set for \\(G\\) if every two distinct vertices of \\(G\\) are doubly resolved by some two vertices of \\(S\\). The minimal doubly resolving set of vertices of graph \\(G\\) is a doubly resolving set with minimum cardinality and is denoted by \\(\\psi(G)\\). In this paper, first, we construct a class of graphs of order \\(2n+ \\Sigma_{r=1}^{k-2}\\text{nm}^r\\), denoted by \\(\\text{LSG}(n,m,k)\\), and call these graphs as the layer Sun graphs with parameters \\(n\\), \\(m\\), and \\(k\\). 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