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Langenbruch} [Manuscr. Math. 119, No. 3, 269--285 (2006; Zbl 1101.46026)]. Moreover, they determine the coefficient spaces corresponding to this Hermite expansion. These results are applied to spaces defined by weight functions \\(\\mathcal{S}_{[\\omega]}(\\mathbb{R}^d)\\), with \\([\\omega] = (\\omega)\\) (Beurling setting) or \\([\\omega] = \\{\\omega\\}\\) (Roumieu setting). Therefore, they extend part of the previous work of \\textit{J.-M. Aubry} [J. Lond. Math. Soc., II. Ser. 78, No. 2, 392--406 (2008; Zbl 1170.46007)] to the several variables case. As a consequence, the authors are able to generalize their previous study about the nuclearity of the space \\(\\mathcal{S}_{(\\omega)}(\\mathbb{R}^d)\\) to global spaces of ultradifferentiable functions defined by weight matrices. In particular, the authors characterize in a very general way when the Hermite functions are contained in the classes considered in the paper and this fact is closely related to classes being non-trivial. 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