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The main objects of the study are the original Weyl-Titchmarsh function \\(m_\\infty\\) and its linear-fractional transformation \\(m_\\alpha\\), as well as their reciprocals \\(1/m_\\infty\\) and \\(1/m_\\alpha\\). The authors show that these functions can be realized as the impedance functions of the corresponding, explicitely given, Schr\u00f6dinger \\(L\\)-systems. Moreover, these realizing \\(L\\)-systems share the same dissipative Schr\u00f6dinger operator and are related to various boundary problems (Dirichlet, Neumann and mixed).  In the case of non-negative symmetric Schr\u00f6dinger operators, the authors obtain additional properties of the realizations, in particular the authors describe the cases when the realizing Schr\u00f6dinger \\(L\\)-systems are accretive.  To treat the problem of uniqueness, the authors give the general definition of equality for \\(L\\)-systems and prove that two Schr\u00f6dinger \\(L\\)-systems with the same underlying parameters are equal if and only if their impedance functions match. Also a generaliztion of this result is given to establish a condition for two Schr\u00f6dinger \\(L\\)-systems to share the same main operator in terms of the Donoghue transform. 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