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However, in the literature there are experimental observations of non stress-free junctions between martensitic plates, where the compatibility theory fails to be predictive. In this work, we focus on \\(V_{II}\\) junctions, which are non stress-free interfaces between different martensitic variants experimentally observed in \\(\\mathrm{Ti}_{74}\\mathrm{Nb}_{23}\\mathrm{Al}_3\\). We first motivate the formation of some non stress-free junctions by studying the two well problem under suitable boundary conditions. We then give a mathematical characterisation of \\(V_{II}\\) junctions within the theory of elasto-plasticity, and show that for deformation gradients as in \\(\\mathrm{Ti}_{74}\\mathrm{Nb}_{23}\\mathrm{Al}_3\\) our characterisation agrees with experimental results. Furthermore, we are able to prove that, under suitable hypotheses that are verified in the study of \\(\\mathrm{Ti}_{74}\\mathrm{Nb}_{23}\\mathrm{Al}_3, V_{II}\\) junctions are strict weak local minimisers of a simplified energy functional for martensitic transformations in the context of 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