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Dynamical characteristics of the fractional-order system are analyzed fully through numerical simulations, mainly including finite-time local Lyapunov exponents, bifurcation diagram, and the basins of attraction. In particular, the system can generate diverse coexisting attractors varying with different orders, which presents ample and complex dynamic characteristics. And there is great potential for secure communication. Then electronic circuit of the fractional-order system is designed to help verify its effectiveness. What is more, taking the disturbances into account, a finite-time synchronization of the fractional-order chaotic system without equilibrium is achieved and the improved controller is proven strictly by applying finite-time stable theorem. Eventually, simulation results verify the validity and rapidness of the proposed method. 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