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The main result says that if \\(X\\) is a Fano manifold of dimension at least \\(7\\) and of Picard number \\(1\\), consider \\(H\\) the fundamental divisor and \\(i_X\\) the index of \\(X\\), then \\[ (c_2(X)\\cdot H^{n-2})/(H^n)\\geq \\begin{cases} \\frac{11n-16}{6n-6} & \\text{ if } i_X=2;\\\\ \\frac{i_X(i_X-1)}{2} & \\text{ if } 3\\leq i_X\\leq n. \\end{cases} \\] As an application, this paper shows that if \\(X\\) is a Fano manifold of dimension \\(n \\geq 4\\) and index \\(n-3\\), then \\(h^0(X, H) \\geq n-2\\), where \\(H\\) is the fundamental divisor; and \\(H^{2n-2}(X,\\mathbb{Z})\\) is generated by curves.  Then this paper studies when \\(|-mK_X|\\) is free or gives a birational map for a weak Fano variety \\(X\\) with canonical Gorenstein singularites. 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