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More precisely, let \\(\\mathfrak{H}\\) be a Hilbert space and \\(A,B\\) be self-adjoint operators in \\(\\mathfrak{H}\\) such that their resolvent difference is trace class. Then the wave operators \\(W_{\\pm}(A,B)\\) exist and are complete. Let \\(S(A,B):=W_+(A,B)^*W_-(A,B)\\) be the scattering system, and \\((S(A,B,\\lambda))_{\\lambda\\in\\mathbb{R}}\\) be the scattering matrix, i.e. the family of unitary multiplication operators representing \\(S(A,B)\\) in the absolutely continuous part of \\(A\\). Then  \\[  S(A,B,\\lambda) = I - 2i \\sqrt{\\mathrm{Im } M(\\lambda+i0)} M(\\lambda+i0)^{-1} \\sqrt{\\mathrm{Im } M(\\lambda+i0)}  \\]  for a.e.\\ \\(\\lambda\\in\\mathbb{R}\\), where \\(M\\) is the Weyl function, see Theorem 3.1.  This result is then applied to Schr\u00f6dinger operators with Dirichlet, Neumman, and Robin boundary conditions on exterior domains in \\(\\mathbb{R}^2\\) and \\(\\mathbb{R}^3\\) with \\(C^\\infty\\)-boundary, and to Schr\u00f6dinger operators with singular potentials supported on curves and hypersurfaces in \\(\\mathbb{R}^2\\) and \\(\\mathbb{R}^3\\).  The main tool is a formulation of the problem by means of generalized boundary 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