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Such an instanton bundle is a rank-two Hermitian vector bundle with a unitary connection of anti-self-dual curvature. Special instanton bundles, namely the so-called instantons with quadrupole symmetry, or briefly symmetric instantons, have been introduced a few years ago by \\textit{J. E. Avron}, \\textit{L. Sadun}, the second author and \\textit{B. Simon} [Commun. Math. Phys. 124, No. 4, 595-627 (1989; Zbl 0830.57020)]. It has become known, in the meantime, that the classification of symmetric instantons is given by pairs \\((n_+,n_-)\\) of odd positive integers related to the second Chern number of the instanton by the formula \\(8c_2= n^2_+-n^2_-\\), and that there are no symmetric instantons with \\(n_-\\geq 3\\) [cf. \\textit{L. Sadun} and the second author, ibid. 145, No. 2, 363-391 (1992; Zbl 0765.53020)].   In the present article, the authors provide a constructive classification of all symmetric instantons of the solely interesting type \\((n_+,1)\\). Using the Ward correspondence between instantons and holomorphic vector bundles on \\(P^3_{\\mathbb{C}}\\) as well as the Atiyah-Drinfeld-Hitchin-Manin construction (ADHM construction) via monads [cf. \\textit{M. F. Atiyah}, \\textit{N. J. Hitchin} and \\textit{I. M. Singer}, Proc. R. Soc. Lond., Ser. A 362, 425-461 (1978; Zbl 0389.53011)], it is proved that there is precisely one symmetric instanton on each of the bundles over \\(S^4\\) with quadrupole symmetry of type \\((n_+,1)\\), for any odd natural number \\(n_+\\), and that its ADHM monad can be explicitly constructed.   In view of its constructive proof, this theorem is particularly valuable for a deeper understanding of the geometry of the Yang-Mills equations over \\(S^4\\), especially with regard to the problem of the existence of solutions that are neither selfdual nor anti-selfdual.   Also, instantons with quadrupole symmetry have recently gained a remarkable significance due to their link with isomonodromic deformations of linear ordinary differential equations and with certain Einstein metrics [cf. \\textit{N. Hitchin}, J. Differ. Geom. 42, No. 1, 30-112 (1995; Zbl 0861.53049)].   The paper is written in a very thorough, rigorous and lucid manner, providing a welcome amount of motivating remarks, background material and illustrating 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