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The diffusion term \\(\\nabla \\cdot (a(\\mathbf{x}, t)\\nabla u)\\) is discretized by the novel expanded mixed method, whose gradient belongs to the square integrable space instead of the classical \\(\\mathbf{H}(\\text{div}; \\Omega)\\) space and the hyperbolic part \\(d(\\mathbf{x})(\\partial u/\\partial t) + \\text\\textbf{c}(\\text\\textbf{x}, t) \\cdot \\nabla u\\) is handled by the characteristic method. For a priori error estimates, some important lemmas based on the novel expanded mixed projection are introduced. The fully discrete error estimates based on backward Euler scheme are obtained. Moreover, the optimal a priori error estimates in \\(L^2\\)- and \\(H^1\\)-norms for the scalar unknown \\(u\\) and a priori error estimates in \\((L^2)^2\\)-norm for its gradient \\(\\lambda\\) and its flux \\(\\sigma\\) (the coefficients times the negative gradient) are derived. 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