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The authors prove that these symmetric spaces have got well-defined tubular structures around reflective totally geodesic submanifolds. For the first action, the principal orbits are proved to be tubular hypersurfaces around the singular orbit \\( \\text{Spin}(9)\\subset F_4\\), which is totally geodesic. Moreover, the whole manifold \\(F_4\\) is shown to be a compact tube around \\( \\text{Spin}(9)\\), the radius of which is equal to \\(\\pi /{\\sqrt{2 \\kappa}}\\), where \\(\\kappa \\) denotes the maximal sectional curvature in \\(F_{4}\\). Similar results were obtained for the isometric action of \\(\\text{Spin} (9)\\) on the symmetric space \\(F_{4}/(\\text{Sp}(3) \\times \\text{Sp}(1))/{\\mathbb {Z}}_{2}\\). The principal orbits are shown to be tubular hypersurfaces around a totally geodesic submanifold, isomorphic to \\(G^+_4({\\mathbb{R}}^9)\\).  Finally, concerning the last action, it is proved that the principal orbits represent the homogeneous space \\(K/(\\text{Spin}(4) \\times \\text{Spin}(3))/ {\\mathbb {Z}}_{2}\\) (here, \\(K\\) denotes the symmetric subgroup of \\(F_{4}\\) that is isometric to \\(\\text{Spin}(3) \\times \\text{Spin}(1) / {\\mathbb{Z}}_{2}\\)). The authors obtain a simple method to calculate the volumes of the symmetric spaces \\(F_{4}\\), \\(F_{4}/(\\text{Sp}(3) \\times \\text{Sp}(1))/{\\mathbb {Z}_{2}}\\) and \\(F_{4}/ \\text{Spin}(9)\\). As an application of these results, the authors show how the volumes of \\(F_4\\), \\(F_4/(\\text{Sp}(3) \\times{\\text{Sp}(3)/{\\mathbb{Z}_{2}}}\\) and of the octonion projective plane \\({\\mathbb{O}}\\mathbb{P}^2\\) can be computed using the general formulae of the volumes of 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