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For each \\(K\\in M_{n}(\\mathbb{F})\\) the set of all invertible \\(A\\in M_{n}(\\mathbb{F)}\\) such that \\(A^{\\top}KA=K\\) is called the \\(K\\)-orthogonal group. The authors are interested in characterizing the class \\(\\Xi_{n}\\) of matrices \\(K\\) for which the \\(K\\)-orthogonal group consists of matrices of determinant \\(1\\); classically, it is known that all skew-symmetric matrices lie in \\(\\Xi_{n}\\). In general, define \\(K_{s}:=\\frac{1}{2}(K+K^{\\top})\\) and \\(K_{w}:=\\frac{1}{2}(K-K^{\\top})\\).   The main theorem shows that the following are equivalent: \\(K\\in\\Xi_{n}\\); the matrix pencil \\(K_{w}-\\lambda K_{s}\\) is regular and its Weierstrass (or Kronecker) canonical form has no Jordan block of odd dimension associated with the eigenvalue \\(0\\); there exists \\(\\lambda _{0}\\in\\mathbb{F}\\) such that \\(K_{w}-\\lambda_{0}K_{s}\\) is invertible, and for each such \\(\\lambda_{0}\\) the matrix \\((K_{w}-\\lambda_{0}K_{s})^{-1}K_{w}\\) has no Jordan block of odd dimension associated with the eigenvalue \\(0\\).   Two alternative characterizations are given as corollaries: (1) \\(K\\in\\Xi_{n}\\) if and only if \\(K\\) is not congruent to a block diagonal matrix with a block of odd dimension; and (2) if \\(K\\) is nonsingular, then \\(K\\in\\Xi_{n}\\) if and only if \\(K^{-1}K_{w}\\) has no Jordan block of odd dimension associated with the eigenvalue 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