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The algorithm described herein uses \\(\\text{O}(B)\\) operations to compute the Fourier coefficients of a function whose Fourier expansion uses only (the \\(\\text{O}(B^3)\\)) spherical harmonics of degree at most \\(B\\). This compares very favourably with the direct \\(\\text{O}(B^6)\\) algorithm derived from a basic quadrature rule on \\(\\text{O}(B^3)\\) sample points. The efficient Fourier transform also makes possible the efficient calculation of convolution over \\(\\text{SO}(3)\\) which has been used as the analytic engine for some new approaches to searching 3D databases: \\textit{Funkhouser} et al. [ACM Trans Graph. 83--105 (2003)]; \\textit{Kazhdan} et al. [Eurographics Symposium in Geometry Processing, 167--175 (2003)]. The implementation is based on the ``Separation of variables'' of \\textit{D. K. Maslen} and \\textit{D. N. Rockmore} [Workshop on groups and computation, DIMACS, Ser. Discrete Math. Theor. Comput. Sci. 28, 183--237 (1997; Zbl 0892.20008)]. In conjunction with the techniques developed for the efficient computation of orthogonal polynomial expansions by \\textit{J. R. Driscoll}, \\textit{D. J. Healy jun.} and \\textit{D. N. Rockmore} [SIAM J. Comput. 26, No. 4, 1066--1099 (1997; Zbl 0896.65094)], the fast \\(\\text{SO}(3)\\) algorithm can be improved to give an algorithm of complexity \\(O(B^3\\log^2 B)\\), but at a cost in numerical reliability. Numerical and empirical results are presented establishing the empirical stability of the basic algorithm. 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