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Determine all possibilities for \\(X\\), \\(D\\) and \\(V\\). For \\(D\\) irreducible, i.e. \\(b_2(V)=1\\), and \\(X=\\mathbb C^3\\), the complete list was given in 1993 by \\textit{M. Furushima} [Math. Ann. 297, No. 4, 627--662 (1993; Zbl 0788.32022)], cf. also \\textit{T. Peternell} and \\textit{M. Schneider} [Math. Ann. 280, No. 1, 129--146 (1988; Zbl 0651.14025)]. The author points out that the condition \\(b_2(V)=1\\) already implies \\(X=\\mathbb C^3\\).  The main result of the paper under review is a complete solution of the classification problem under the assumption \\(b_2(V)=2\\), \\(D=D_1\\cup D_2\\), and the line bundle \\(K_V+D_1+D_2\\) is not nef. The author presents a list of all possibilities and distinguishes 24 different cases. In general the affine threefold \\(X\\) is isomorphic to \\(\\mathbb C^3\\) but in some cases \\(X\\) is only diffeomorphic to \\(\\mathbb C^3\\). The proof is essentially based on Mori theory and in particular on the classification of Fano threefolds with second Betti number at least two, given by \\textit{S. Mori} and \\textit{S. Mukai} [Manuscr. Math. 36, 147--162 (1981); erratum ibid. 110, 407 (2003; Zbl 0478.14033), see also Proc. Symp., Tokyo 1981, Adv. Stud. 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